Peer-Reviewed Journal Details
Mandatory Fields
Crepin, C;Shafizadeh, N;Chin, W;Galaup, JP;McCaffrey, JG;Arabei, SM
2010
May
Low Temperature Physics
Unveiled optical properties of tetrapyrollic pigments in cryogenic environments
Published
7 ()
Optional Fields
VIBRONIC SPECTRA PORPHYRINS MATRIX FLUORESCENCE PHTHALOCYANINES SPECTROSCOPY RESONANCE SYMMETRY
36
451
457
An unexpected phenomenon was revealed in the laser induced fluorescence spectra of free-base (H(2)Pc) and zinc (ZnPc) phthalocyanines trapped in rare gas and nitrogen matrices under a moderate increase in the laser intensity. In all matrices the intensity of an emission band near 755 nm increased drastically when pumping the S(1)<- S(0) transition. This observation was assigned to stimulated emission in a four-level scheme involving a vibronic transition from the lowest electronic state to a vibrational level of the ground state. In the present work, we expose new similar results obtained with porphyrin molecules, i.e. tetra-benzoporphin (TBP). With free-base H(2)TBP, stimulated emission was observed in Ar or N(2) matrices, but not in Xe matrices. A possible reason could be a fast inter-system crossing rate due to the heavy atom effect induced by Xe. We also report the observation of persistent burnt spectral holes, although the low efficiency of this process is not competitive with stimulated emission and no decrease of the stimulated emission with time was observed. With ZnTBP no stimulated emission could be recorded but the appearance of rather strong phosphorescence was noticed. Similar studies focusing on the stimulated emission phenomenon is that they should allow new insights into site effects and site selectivity. (C) 2010 American Institute of Physics.
MELVILLE
1063-777X
10.1063/1.3432263
Grant Details