Peer-Reviewed Journal Details
Mandatory Fields
Fenelon, AM;Breslin, CB
2002
October
Electrochimica Acta
The electrochemical synthesis of polypyrrole at a copper electrode: corrosion protection properties
Published
144 ()
Optional Fields
POLYANILINE FILMS MILD-STEEL BENZOTRIAZOLE IMPEDANCE IRON DERIVATIVES INHIBITORS MONOLAYER
47
4467
4476
Pyrrole was successfully electropolymerized at a copper electrode in a near neutral sodium oxalate solution to generate a homogeneous and adherent polypyrrole film. The growth of these films was facilitated by the initial oxidation of the copper electrode in the oxalate solution to generate a copper oxalate pseudo-passive layer. This layer was sufficiently protective to inhibit further dissolution of the copper electrode and sufficiently conductive to enable the electropolymerization of pyrrole at the interface, and the generation of an adherent polypyrrole film. These films remained stable and conducting for periods exceeding eight days and exhibited significant corrosion protection properties in acidified and neutral 0.1 mol dm(-3) NaCl solutions even on polarization to high anodic potentials. (C) 2002 Elsevier Science Ltd. All rights reserved.
OXFORD
0013-4686
Grant Details