Peer-Reviewed Journal Details
Mandatory Fields
McMahon, S;Rochford, J;Halpin, Y;Manton, JC;Harvey, EC;Greetham, GM;Clark, IP;Rooney, AD;Long, C;Pryce, MT
2014
October
Physical Chemistry Chemical Physics
Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)(5)CrC(NC4H8)CH3]
Published
8 ()
Optional Fields
CYCLIZATION REACTIONS ORGANIC-SYNTHESIS MATRIX-ISOLATION METAL-COMPLEXES CHROMIUM STIMULATION MECHANISM DENSITY STATES DFT
16
21230
21233
Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)(5)CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.
CAMBRIDGE
1463-9076
10.1039/c4cp03758h
Grant Details