Peer-Reviewed Journal Details
Mandatory Fields
Benjamin S.;Krämer T.;Levason W.;Light M.;Macgregor S.;Reid G.
2016
June
Journal of the American Chemical Society
A Pd(0) Tetrahedron with μ3-Bridging Trimethylantimony Ligands
Published
2 ()
Optional Fields
138
22
© 2016 American Chemical Society. The palladium(II) chlorostibine complex [PdCl 2 (SbMe 2 Cl) 2 ] 2 has a dimeric structure in the solid state, stabilized by hyper-coordination at the Lewis amphoteric Sb centers. Reaction with 8 equiv of MeLi forms [Pd 4 (μ 3 -SbMe 3 ) 4 (SbMe 3 ) 4 ], whose structure comprises a tetrahedral Pd(0) core with four terminal SbMe 3 ligands and four μ 3 -SbMe 3 ligands, one capping each triangular Pd 3 face. Density functional theory calculations, supported by energy decomposition analysis and the natural orbitals for chemical valence scheme, highlight significant donor and acceptor orbital contributions to the bonding between both the terminal and the bridging SbMe 3 ligands and the Pd 4 core.
0002-7863
10.1021/jacs.6b04060
Grant Details