Peer-Reviewed Journal Details
Mandatory Fields
Sung, S;Joachim, T;Kramer, T;Young, RD
2017
August
Organometallics
Protonolysis of an alpha-Hydroxyl Ligand for the Generation of a PCcarbeneP Pincer Complex and Subsequent Reactivity Studies
Published
4 ()
Optional Fields
C-H ACTIVATION METALLACYCLIC MANGANESE MOLECULAR-STRUCTURE CARBENE RUTHENIUM IRIDIUM RHODIUM NICKEL PALLADIUM STABILIZATION
36
3117
3124
A rhodium alpha-hydroxylalkyl complex (1) reacts rapidly with Brookhart's acid, [H(OEt2)(2)][B(3,5-(CF3),C6H3)(4)], to generate a cationic PCcarbeneP complex (2). Complex 2 can also be accessed from salt metathesis of an alpha-hydroxyalkyl hydrochlorido rhodium(III) complex (4) with Na[B(3,5-(CF3)(2)-C6H3)(4)]. The reactivity of compound 2 is explored through a series of reactions with various nucleophilic and electrophilic reagents.
WASHINGTON
0276-7333
10.1021/acs.organomet.7b00461
Grant Details