Peer-Reviewed Journal Details
Mandatory Fields
McKay A.;Krämer T.;Rees N.;Thompson A.;Christensen K.;Macgregor S.;Weller A.
2017
January
Organometallics
Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]
Published
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Optional Fields
36
1
22
25
© 2016 American Chemical Society. Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H8)][BArF 4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2- C7H12)][BArF 4] by a single-crystal to single-crystal reaction, as characterized by Xray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
0276-7333
10.1021/acs.organomet.6b00645
Grant Details