Peer-Reviewed Journal Details
Mandatory Fields
Zaher H;Ashley AE;Irwin M;Thompson AL;Gutmann MJ;Krämer T;O'Hare D;
2013
October
Chemical Communications
Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].
Published
20 ()
Optional Fields
49
84
The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H···H) bond within a hydrogenated FLP system.
1364-548X
10.1039/c3cc45889j
Grant Details